2-Amino-N-(2-hydroxy-3-methoxybenzylidene)aniline
نویسندگان
چکیده
In the title compound, C(14)H(14)N(2)O(2), the dihedral angle between the two benzene rings is 9.67 (10)°. Two intra-molecular O-H⋯N and N-H⋯N hydrogen bonds involving the hydr-oxy and amino groups generate S(6) and S(5) ring motifs, respectively. In the crystal structure, N-H⋯O hydrogen bonds link neighboring mol-ecules. Mol-ecules are also stacked in a head-to-tail fashion along the c axis through π-π inter-actions [centroid-centroid separation of 3.7357 (12) Å] and are further linked by weak inter-molecular C-H⋯π inter-actions, giving a zigzag arrangement along the b axis.
منابع مشابه
6-Acetoxymethyl-3-[(2-hydroxy-3-methoxybenzylidene)amino]-3,4,5,6-tetrahydro-2H-pyran-2,4,5-triyl triacetate
The title compound, C(22)H(27)NO(11), was synthesized by the reaction of 4,5-diacet-oxy-6-acetoxy-methyl-3-amino-tetra-hydro-pyran-2-yl acetate and 2-hydr-oxy-3-methoxy-benzalde-hyde in ethanol. The mol-ecule contains two six-membered rings, one of which is in a chair conformation, and an intra-molecular O-H⋯N hydrogen bond is present.
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